It was discontinued in 2008 for manufacturing reasons, not safety concerns
Lab Invest 81(5):645672 Ebisch IMW, van Heerde WL, Thomas CMG, van der Put N, Wong WY, Steegers-Theunissen RPM (2003) C677T methylenetetrahydrofolate reductase polymorphism interferes with the effects of folic acid and zinc sulfate on sperm concentration
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But once opened, sterile water has no preservative protection any contamination from the air or the syringe needle can begin multiplying